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Chemistry for Sustainable Development

2004 year, number 5

Interlaboratory Comparison of Methods for Analyzing the Ion Composition of Atmospheric Precipitates and Aerosols

B. S. SMOLYAKOV1, T. V. KHODJER2, M. P. SHINKORENKO1, L. A. PAVLYUK1, S. N. FILIMONOVA1, V. M. DOMYSHEVA2, L. P. GOLOBOKOVA2, O. G. NETSVETAEVA2 and T. V. POGODAEVA2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences,
Pr. Akademika Lavrentyeva 3, Novosbirsk 630090 (Russia) E-mail: ecol@che.nsk.su
2Limnological Institute, Siberian Branch of the Russian Academy of Sciences, Ul. Ulan-Batorskaya 3, Irkutsk 664033 (Russia)
Pages: 543-551

Abstract

This paper presents the results of interlaboratory comparison of analytical data on ion composition for two artificial rain and 80 atmospheric aerosol samples taken on AFA-KhA and Whatman filters. The largest error of analysis is reported for the HCO3- and NH3+ ions. Optimization of the water extraction procedures and improvement of water used for this purpose will reduce the systematic error in aerosol analysis.